Reactivity and Mechanistic Studies of the Reactions of Chlorodiphenylphosphine and Its Oxide with Methyl Glyoxylate, Glyoxylate Oximes, and Methyl Cyanoformate

• Type: Article in International Scientific Journal
• Date: 2015

Authors

Carlos A D Sousa (Author) Other; Carlos F R A C Lima (Author) Other; Ivo E Sampaio Dias (Author) Other; Xerardo Garcia Mera (Author) Other; Jose E Rodriguez Borges (Author) FCUP

Journal

Title: Heteroatom Chemistry

Vol. 26

Pages: 249-256

ISSN: 1042-7163

Publisher: Wiley-Blackwell

Indexing

ISI Web of Knowledge - 5 Citations

Scopus - 5 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-00G-D8R

DOI: 10.1002/hc.21255

Abstract (EN): In this work, we describe the reactivity of chlorodiphenylphosphine and its oxide, as well as diphenylphosphine, with some glyoxylate derivative systems: methyl glyoxylate, methyl or 8-phenylneomenthyl glyoxylate oximes, and methyl cyanoformate. By analyzing the reactions outcomes and with the aid of computational chemistry, we propose some reaction mechanisms and molecular rearrangements.

Language: English

Type (Professor's evaluation): Scientific