MUONIUM SUBSTITUTED ORGANIC FREE-RADICALS IN LIQUIDS - MUON ELECTRON HYPERFINE COUPLING-CONSTANTS OF ALKYL AND ALLYL RADICALS

• Type: Article in International Scientific Journal
• Date: 1982

Authors

RODUNER, E (Author) Other; STRUB, W (Author) Other; BURKHARD, P (Author) Other; HOCHMANN, J (Author) Other; PERCIVAL, PW (Author) Other; FISCHER, H (Author) Other; RAMOS, M (Author) FCUP; WEBSTER, BC (Author) Other

Journal

Title: Chemical Physics

Vol. 67

Pages: 275-285

ISSN: 0301-0104

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 87 Citations

Scopus - 83 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-005-6GJ

DOI: 10.1016/0301-0104(82)85189-6

Abstract (EN): Muonium substituted free radicals are observed by muon spin rotation when positive muons are stopped in liquid olefins and dienes. From muon precession the isotropic muon-electron hyperfine coupling constants have been determined for 44 radicals and analyzed to yield the radical structures. Primary, from mono-olefins, and mainly allylic radicals from conjugated dienes. They are formed by addition of the light hydrogen isotope muonium (Mu = ¿ + the relations between coupling constants and radical structures follow the principles known for the analogous H substituted radicals. Further, the regi to that of H atoms. © 1982.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 11