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MUONIUM SUBSTITUTED ORGANIC FREE-RADICALS IN LIQUIDS - MUON ELECTRON HYPERFINE COUPLING-CONSTANTS OF ALKYL AND ALLYL RADICALS

Title
MUONIUM SUBSTITUTED ORGANIC FREE-RADICALS IN LIQUIDS - MUON ELECTRON HYPERFINE COUPLING-CONSTANTS OF ALKYL AND ALLYL RADICALS
Type
Article in International Scientific Journal
Year
1982
Authors
RODUNER, E
(Author)
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STRUB, W
(Author)
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BURKHARD, P
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HOCHMANN, J
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PERCIVAL, PW
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FISCHER, H
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RAMOS, M
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WEBSTER, BC
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Journal
Title: Chemical PhysicsImported from Authenticus Search for Journal Publications
Vol. 67
Pages: 275-285
ISSN: 0301-0104
Publisher: Elsevier
Scientific classification
FOS: Natural sciences > Chemical sciences
Other information
Authenticus ID: P-005-6GJ
Abstract (EN): Muonium substituted free radicals are observed by muon spin rotation when positive muons are stopped in liquid olefins and dienes. From muon precession the isotropic muon-electron hyperfine coupling constants have been determined for 44 radicals and analyzed to yield the radical structures. Primary, from mono-olefins, and mainly allylic radicals from conjugated dienes. They are formed by addition of the light hydrogen isotope muonium (Mu = ¿ + the relations between coupling constants and radical structures follow the principles known for the analogous H substituted radicals. Further, the regi to that of H atoms. © 1982.
Language: English
Type (Professor's evaluation): Scientific
No. of pages: 11
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