Synthesis and Hydrolytic Studies on the Air-Stable [(4-CN-PhO)(E)P(mu-(NBu)-Bu-t)](2) (E = O, S, and Se) Cyclodiphosphazanes

• Type: Article in International Scientific Journal
• Date: 2015

Authors

Yan X Shi (Author) Other; Rong Z Liang (Author) Other; Katherine A Martin (Author) Other; Nicholas Weston (Author) Other; Silvia Gonzalez Calera (Author) Other; Rakesh Ganguly (Author) Other; Yongxin X Li (Author) Other; Yunpeng P Lu (Author) Other; Antonio J M Ribeiro (Author) Other; Maria J Ramos (Author) FCUP; Pedro A Fernandes (Author) FCUP; Felipe Garcia (Author) Other

Journal

Title: Inorganic Chemistry

Vol. 54

Pages: 6423-6432

ISSN: 0020-1669

Publisher: American Chemical Society

Indexing

ISI Web of Knowledge - 22 Citations

Scopus - 21 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-00G-D86

DOI: 10.1021/acs.inorgchem.5b00735

Abstract (EN): Reaction of 4-CN-PhOH with [ClP(mu-(NBu)-Bu-t)](2) (1) (2:1 ratio) in the presence of Et3N produced the functionalized cydodiphosph(III/III)azane [(4-CN-PhO)P-(mu-(NBu)-Bu-t)](2) (2). Oxidation of 2 produced cydodiphosph(V/V)azanes [(4-CN-PhO)(E)P(mu-(NBu)-Bu-t)](2) [E = O (3), S (4), and Se (5)]. This is the first example of a series of cydodiphosph(V/V)azane derivatives obtained from a single cydophosph(III/III)azane precursor where all the accessible chalcogen oxidized products are air-stable over prolonged periods of time.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 10