Effect of the temperature on the physical properties of the pure ionic liquid 1-ethyl-3-methylimidazolium methylsulfate and characterization of its binary mixtures with alcohols

• Type: Article in International Scientific Journal
• Date: 2014

Authors

Patricia F. Requejo (Author) Other; Emilio J. González (Author) FEUP; Eugénia A. Macedo (Author) FEUP; Ángeles Domínguez (Author) Other

Journal

Title: Journal of Chemical Thermodynamics

Vol. 74

Pages: 193-200

ISSN: 0021-9614

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 23 Citations

ISI Web of Science

Scopus - 38 Citations

Scientific classification

CORDIS: Technological sciences

FOS: Engineering and technology

Associated Projects

LA 20 - PROJECTO ESTRATÉGICO - LA 20 - 2013-2014

Other information

Authenticus ID: P-009-DS8

DOI: 10.1016/j.jct.2014.01.030

Abstract (EN): Experimental density, speed of sound, refractive index and viscosity data of the pure ionic liquid 1-ethyl3-methylimidazolium methylsulfate, [EMim][MSO4], were measured as a function of temperature from T = (293.15 to 343.15) K, every 5 K, and atmospheric pressure. Density, speed of sound and refractive index data were satisfactorily correlated with a linear equation, while viscosity data were fitted to the Vogel-Fulcher-Tamman (VFT) equation. Besides, from the experimental density values, the thermal expansion coefficient, alpha, was calculated. Furthermore, density and speed of sound for the binary systems of {methanol, or ethanol, or 1-propanol, or 2-propanol, or 1-butanol, or 1-pentanol + [EMim][MSO4]} were experimentally determined over the whole composition range, at T = (288.15, 298.15 and 308.15) K and p = 0.1 MPa. These properties were used to calculate the corresponding excess molar volumes and excess molar isentropic compressions, which were satisfactorily fitted to the Redlich-Kister equation. Finally, a comparison with available literature data was also carried out and the obtained results are discussed in terms of interactions and structure factors in these binary mixtures.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 8