The synthesis of novel polymer-bound calix[4]arenes

• Type: Article in International Scientific Journal
• Date: 2004

Authors

Barata, PD (Author) Other; Costa, AI (Author) Other; Granja, P (Author) Other; Prata, JV (Author) Other

Journal

Title: Reactive and Functional Polymers

Vol. 61

Pages: 147-151

ISSN: 1381-5148

Publisher: Elsevier

Indexing

ISI Web of Knowledge - 16 Citations

Scopus - 16 Citations

Scientific classification

FOS: Engineering and technology > Chemical engineering

Other information

Authenticus ID: P-000-DKH

DOI: 10.1016/j.reactfunctpolym.2004.04.005

Abstract (EN): Two simple and efficient procedures for the synthesis of linear and cross-linked polymers containing hydrophobic and hydrophilic lower rim derivatives of p-tert-butylcalix[4]arenes are described. The target polymers were prepared either through the direct attachment of 25,26,27,28-tetrahydroxy-p-tert-butylcalix[4]arene (1), or its tripropoxy (2) and tetracarboxymethoxy (4) derivatives, to light cross-linked Merrifield's resins (1-2% DVB) or via radical addition copolymerisation of 25,26,27-tripropoxy-28-(4-vinyl-benzyloxy)-p-tert-butylcalix[4]arene (11) with styrene and a crosslinking agent. (C) 2004 Elsevier B.V. All rights reserved.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 5