Flow injection analysis of fluoride in electroplating baths with potentiometric detection

• Type: Article in International Scientific Journal
• Date: 1998

Authors

Perez Olmos, R (Author) Other; Etxebarria, MB (Author) Other; Lima, JLFC (Author) FFUP; Montenegro, MCBSM (Author) FFUP

Journal

Title: Fresenius' Journal of Analytical Chemistry

Vol. 362

Pages: 230-233

ISSN: 0937-0633

Publisher: Springer

Indexing

ISI Web of Knowledge - 4 Citations

Scopus - 4 Citations

Scientific classification

FOS: Natural sciences > Chemical sciences

Other information

Authenticus ID: P-001-75Z

DOI: 10.1007/s002160051065

Abstract (EN): A high dispersion FIA system with a fluoride selective and a double junction reference electrode in cascade arrangement was developed for the determination of the fluoride content in chromium electroplating baths. The analyses of seven synthetic baths prepared in the laboratory and two samples provided by the industry gave results with a mean recovery value of 100.5%, and a mean variation coefficient of 1.6%. These data were better than those obtained by the EDTA complexometric titration, the reference technique, with a mean recovery of 94.0% and a mean variation coefficient of 7.5%. The sampling rate for the FIA manifold was 20 samples per hour.

Language: English

Type (Professor's evaluation): Scientific

No. of pages: 4